So you are talking about carrying medium range/BVR/Fox1 missiles AND A-G ordnance at the same time.
M2000: You are correct, the S530D are not deployable if you carry A-G ordnance
F1CE/EE: You will be able to carry R530 and any A-G ordnance at the same time and deploy them.
The F1 has a pretty basic weapon selection panel, and no digital FCS contrary to the 2000.
In the F1 you basically just select the station, the aircraft doesn't care what is attached to it.